Hagen Puppy Trainer MSDS

MATERIAL SAFETY DATA SHEET

ROLF C. HAGEN INC., 20500 TRANS CANADA HWY.,
BAIE d'URFE, QUEBEC, H9X 0A2

D-110 - Hagen Puppy Trainer

Section I. Product identification and uses Section II. Hazardous ingredients

Product name       - Hagen Puppy Trainer Ammonium Carbonate - 506-87-6
  5 - 10 %
  TLV - No Data

Chemical formula - Mixture

Chemical Name - Anti-flca Carpet Protector Spray

Material uses - Train puppy - Housebreaking Aid

Section III. Physical data

Physical state and appearance/odor Clear liquid Ammonia odor

pH Not available

Percent volatile 82%

Freezing point Not Available

Boiling point 105° C

Specific gravity No Data

Vapor density Not available

Vapor pressure No Data

Evaporation rate (Butyl Acetate = 1) No Data

Solubility in water Complete

Section IV. Fire and explosion data

Flash Point (tag Close cup) No Data

Flammable limits in air No Data

Means of extinction Water fog, CO₂, Foam, Dry Chemical

Special fire fighting procedures Wear self-contained breathing apparatus in confined areas or when exposed to combustion products.

Unusual fire and explosion hazards No Data

Section V. Reactivity data

Stable

Conditions to avoid Strong base, strong acids, Nitrites

Material to avoid Nitrites; reaction takes place even at room temperature and proceeds with a flame or even explosion

Hazardous products of decomposition Ammonia (NH₃) gas, CO₂

Dangerous Polymerization Will not occur

Section VI. Toxicological properties

Routes of entry

Eye Contact May cause irritation

Skin Contact May cause irritation

Inhalation Vapors and mists irritate the respiratory tract.

Ingestion May cause adverse health effects

Exposure limit of material Oral: DL50 (rat) = 20000 mg/Kg
Skin: DL50 (rabbit) No Data

Effects of chronic overexposure No Data

Medical conditions generally aggravated by exposure No Data

Section VII. First aid measures

Eye contact Immediately flush eyes with large amounts of water for at least 15 minutes holding lids apart to ensure flushing of the entire surface. Washing eyes within 1 minute is essential to achieve maximum effectiveness. Seek medical attention.

Skin contact Wash thoroughly with soap and water. Remove contaminated clothing and footwear. Wash clothing before re-use. Seek medical attention if irritation should develop.

Inhalation Remove to fresh air. Give artificial respiration if not breathing. Get immediate medical attention.

Ingestion If swallowed DO NOT induce vomiting. Small amounts of this liquid drawn into the lungs from swallowing or vomiting may cause severe health effects (e.g. BRONCOPNEUMONIA OR PULMONARY EDEMA). Seek medical attention. Never give anything by mouth to an unconscious person.

Section VIII. Preventive measures

Precautionary Measures Use adequate local exhaust ventilation capable of maintaining emissions at the point of use below the PEL

Respiratory Protection Preferred

Protective clothing Long sleeved shirt, trousers, safety shoes, rubber gloves and rubber apron.

Eye Protection Chemical goggles

Other Protective Measures No Data

Section IX. Spill, Leak and Disposal Procedures
Action to take for spills or leaks Wear protective equipment. For small spills or drips, mop or wipe up and dispose of in dot-approved waste containers. For large spills, contain by diking with soil or other non-combustible absorbent materials and then place in dot-approved waste containers; or absorb with non-combustible sorbent material, place residue in dot-approved waste containers. Keep out of sewers, storm drains, surface waters and soil. Comply with all applicable govermental regulations on spill reporting, handling and disposal of waste.

Waste disposal method Dispose of contaminated product and materials used in cleaning up spills or leaks in a manner approved for this material. Consult appropriate federal, provincial and local regulatory agencies to ascertain proper disposal procedures.
NOTE: Empty containers can have residues, gases and mists and are subject to proper waste disposal, as above.

Storage and handling Avoid eye and skin contact. Avoid inhaling. Store in a cool, dry and well ventilated location.

Section IX. Special Precautions

Repair and maintenance precautions Do not cut, grind, weld or drill on or near this container.

Other Precautions Containers, even those that have been emptied will retain product residue and vapors. Always obey hazard warnings and handle empty containers as if they were full.

Prepared by
Rolf C. Hagen Inc.
(514) 457-0914 Validated June 22, 1994

Section I. Product identification and uses	Section II. Hazardous ingredients
Product name - Hagen Puppy Trainer	Ammonium Carbonate - 506-87-6 5 - 10 % TLV - No Data
Chemical formula - Mixture
Chemical Name - Anti-flca Carpet Protector Spray
Material uses - Train puppy - Housebreaking Aid

Section III. Physical data
Physical state and appearance/odor	Clear liquid Ammonia odor
pH	Not available
Percent volatile	82%
Freezing point	Not Available
Boiling point	105° C
Specific gravity	No Data
Vapor density	Not available
Vapor pressure	No Data
Evaporation rate (Butyl Acetate = 1)	No Data
Solubility in water	Complete

Section IV. Fire and explosion data
Flash Point (tag Close cup)	No Data
Flammable limits in air	No Data
Means of extinction	Water fog, CO₂, Foam, Dry Chemical
Special fire fighting procedures	Wear self-contained breathing apparatus in confined areas or when exposed to combustion products.
Unusual fire and explosion hazards	No Data

Section V. Reactivity data
Stable
Conditions to avoid	Strong base, strong acids, Nitrites
Material to avoid	Nitrites; reaction takes place even at room temperature and proceeds with a flame or even explosion
Hazardous products of decomposition	Ammonia (NH₃) gas, CO₂
Dangerous Polymerization	Will not occur

Section VI. Toxicological properties
Routes of entry
Eye Contact	May cause irritation
Skin Contact	May cause irritation
Inhalation	Vapors and mists irritate the respiratory tract.
Ingestion	May cause adverse health effects
Exposure limit of material	Oral: DL50 (rat) = 20000 mg/Kg Skin: DL50 (rabbit) No Data
Effects of chronic overexposure	No Data
Medical conditions generally aggravated by exposure	No Data

Section VII. First aid measures
Eye contact	Immediately flush eyes with large amounts of water for at least 15 minutes holding lids apart to ensure flushing of the entire surface. Washing eyes within 1 minute is essential to achieve maximum effectiveness. Seek medical attention.
Skin contact	Wash thoroughly with soap and water. Remove contaminated clothing and footwear. Wash clothing before re-use. Seek medical attention if irritation should develop.
Inhalation	Remove to fresh air. Give artificial respiration if not breathing. Get immediate medical attention.
Ingestion	If swallowed DO NOT induce vomiting. Small amounts of this liquid drawn into the lungs from swallowing or vomiting may cause severe health effects (e.g. BRONCOPNEUMONIA OR PULMONARY EDEMA). Seek medical attention. Never give anything by mouth to an unconscious person.

Section VIII. Preventive measures
Precautionary Measures	Use adequate local exhaust ventilation capable of maintaining emissions at the point of use below the PEL
Respiratory Protection	Preferred
Protective clothing	Long sleeved shirt, trousers, safety shoes, rubber gloves and rubber apron.
Eye Protection	Chemical goggles
Other Protective Measures	No Data

Section IX. Spill, Leak and Disposal Procedures
Action to take for spills or leaks	Wear protective equipment. For small spills or drips, mop or wipe up and dispose of in dot-approved waste containers. For large spills, contain by diking with soil or other non-combustible absorbent materials and then place in dot-approved waste containers; or absorb with non-combustible sorbent material, place residue in dot-approved waste containers. Keep out of sewers, storm drains, surface waters and soil. Comply with all applicable govermental regulations on spill reporting, handling and disposal of waste.
Waste disposal method	Dispose of contaminated product and materials used in cleaning up spills or leaks in a manner approved for this material. Consult appropriate federal, provincial and local regulatory agencies to ascertain proper disposal procedures. NOTE: Empty containers can have residues, gases and mists and are subject to proper waste disposal, as above.
Storage and handling	Avoid eye and skin contact. Avoid inhaling. Store in a cool, dry and well ventilated location.

Section IX. Special Precautions
Repair and maintenance precautions	Do not cut, grind, weld or drill on or near this container.
Other Precautions	Containers, even those that have been emptied will retain product residue and vapors. Always obey hazard warnings and handle empty containers as if they were full.